Ammonia → Diallyl 3-aminobenzene-1,2-dicarboxylate

HRID 1736360Notes

Reaction equation

HRID 1736360 reaction equation
[N+:1]([C:4]1[CH:9]=[CH:8][CH:7]=[C:6]([C:10]([O:12][CH2:13][CH:14]=[CH2:15])=[O:11])[C:5]=1[C:16]([O:18][CH2:19][CH:20]=[CH2:21])=[O:17])([O-])=O.C(OC1C=C(C=CC=1[N+]([O-])=O)C(OCC=C)=O)C=C.N>>[NH2:1][C:4]1[CH:9]=[CH:8][CH:7]=[C:6]([C:10]([O:12][CH2:13][CH:14]=[CH2:15])=[O:11])[C:5]=1[C:16]([O:18][CH2:19][CH:20]=[CH2:21])=[O:17]

Participants

4

Reactant 3

HCID 222AmmoniaHCID 19432478Allyl 3-allyloxy-4-nitrobenzoateHCID 19432547Diallyl 3-nitrobenzene-1,2-dicarboxylate

Product 1

HCID 19432564Diallyl 3-aminobenzene-1,2-dicarboxylate

Procedure

The above nitro compound was reduced by the method described in example 1, for the reduction of allyl 3-allyloxy-4-nitrobenzoate, except using an aqueous solution of ammonia in place of sodium bicarbonate in the work-up, to give diallyl 3-aminobenzene-1,2-dicarboxylate.

Sources & evidence

ORD record
ord-819acc3b45f748628abc59eca7529a88
Source dataset
uspto-grants-1996_07
Patent number
US05541178

Reaction notes

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