Allyl 4-chloro-2-nitrobenzoate → Allyl 2-amino-4-chlorobenzoate

HRID 1736368Notes

Reaction equation

HRID 1736368 reaction equation
[Cl:1][C:2]1[CH:13]=[CH:12][C:5]([C:6]([O:8][CH2:9][CH:10]=[CH2:11])=[O:7])=[C:4]([N+:14]([O-])=O)[CH:3]=1.CC1C=CC=C([N+]([O-])=O)C=1C(OCC=C)=O>>[NH2:14][C:4]1[CH:3]=[C:2]([Cl:1])[CH:13]=[CH:12][C:5]=1[C:6]([O:8][CH2:9][CH:10]=[CH2:11])=[O:7]

Participants

3

Reactant 2

HCID 19432485Allyl 4-chloro-2-nitrobenzoateHCID 19432516Allyl 2-methyl-6-nitrobenzoate

Product 1

HCID 19432554Allyl 2-amino-4-chlorobenzoate

Procedure

The above nitro compound was reduced by the method described in example 6, for the reduction of allyl 2-methyl-6-nitrobenzoate, to give allyl 2-amino-4-chlorobenzoate.

Sources & evidence

ORD record
ord-de4ad6978ad04ed0a2807bc206c111c2
Source dataset
uspto-grants-1996_07
Patent number
US05541178

Reaction notes

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