Allyl 2-methyl-6-nitrobenzoate → Allyl 3-allyloxycarbonyl-4-aminobenzoate

HRID 1736369Notes

Reaction equation

HRID 1736369 reaction equation
[CH2:1]([O:4][C:5]([C:7]1[CH:8]=[C:9]([CH:16]=[CH:17][C:18]=1[N+:19]([O-])=O)[C:10]([O:12][CH2:13][CH:14]=[CH2:15])=[O:11])=[O:6])[CH:2]=[CH2:3].CC1C=CC=C([N+]([O-])=O)C=1C(OCC=C)=O>C(O)C>[CH2:1]([O:4][C:5]([C:7]1[CH:8]=[C:9]([CH:16]=[CH:17][C:18]=1[NH2:19])[C:10]([O:12][CH2:13][CH:14]=[CH2:15])=[O:11])=[O:6])[CH:2]=[CH2:3]

Participants

4

Reactant 2

HCID 19432516Allyl 2-methyl-6-nitrobenzoateHCID 19432526Allyl 3-allyloxycarbonyl-4-nitrobenzoate

Product 1

HCID 19432563Allyl 3-allyloxycarbonyl-4-aminobenzoate

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

The above nitro compound was reduced by the method described in example 6, for the reduction of allyl 2-methyl-6-nitrobenzoate, except that the solvent was ethanol, to give allyl 3-allyloxycarbonyl-4-aminobenzoate.

Sources & evidence

ORD record
ord-477af56e757d40b7af8f93260382eb34
Source dataset
uspto-grants-1996_07
Patent number
US05541178

Reaction notes

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