HCID 18673230, compound → HCID 54277997, compound

Participants

Reaction Steps

To a solution of 0.3238 g (1.12 mmol) of (N-t-butylamino)(chloro)diphenylsilane in 50 mL of THF was added 1.500 g (1.12 mmol) of potassium 2,4-dimethylpentadienide. The reaction mixture was stirred overnight. The solvent was removed, the residue was extracted with pentane and filtered. The pentane was removed in vacuo to give the product as a pale yellow oil. The yield was 0.3633 g 93.0%. 1H NMR (C6D6) δ 7.79 (m, 4H), 7.22 (m, 6H), 5.65 (s, 1H), 5.08 (s, 1H), 4.98 (s, 1H), 2.44 (s, 2H), 1.84 (s, 3H), 1.57 (s, 3H), 1.30 (s, 1H), 1.09(s, 9H), (s, 6H). 13C NMR(C6D6)δ 142.7, 138.5, 136.0, 135.8, 129.6, 128.0, 126.5, 113.7, 50.2, 33.9, 27.9, 25.1, 24.5

Provenance & Evidence