HuagongsheHuagongshe Chemistry Print Report · For research reference only
HCID 3735677, compound → HCID 69539742, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | HCID 3735677 | HCID 3735677 | — |
| Catalyst | Nickel | HCID 935 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | HCID 67578464 | HCID 67578464 | — |
| Product | HCID 69539742 | HCID 69539742 | 92% |
Reaction Steps
Then, 9.6 g of 3-benzylcyclohexenone were hydrogenated at room temperature using 1 g of Raney nickel in methanol under hydrogen pressure (3 kg/cm2) until the absorption of hydrogen was stopped. After an organic layer was collected by decantation and concentrated, the residue was purified by column chromatography, thereby obtaining 4.5 g of cis-3-benzylcyclohexanol and 4.5 g of trans-3-benzylcyclohexanol (yield: 92% in total).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05962403 |
| Source dataset | uspto-grants-1999_10 |
| ORD ID | ord-ea1efaf641bf4e29beba64ad181f2807 |
| Source note | uspto-grants-1999_10 |