Benzyltriphenylphosphonium bromide → HCID 53910510, compound

HRID 1739478Notes

Reaction equation

HRID 1739478 reaction equation
[CH2:1]([O:8][C:9]1[C:16]([C:17]2[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=2)=[CH:15][CH:14]=[CH:13][C:10]=1[CH:11]=O)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[Br-].[CH2:24]([P+](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1)[C:25]1[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=1>>[CH2:1]([O:8][C:9]1[C:10]([CH:11]=[CH:24][C:25]2[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=2)=[CH:13][CH:14]=[CH:15][C:16]=1[C:17]1[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

3

Reactant 2

HCID 2734970Benzyltriphenylphosphonium bromideHCID 218409602-(Benzyloxy)-[1,1'-biphenyl]-3-carbaldehyde

Product 1

HCID 53910510HCID 53910510, compound

Procedure

2-Benzyloxy-3-phenylbenzaldehyde was reacted with benzyl triphenylphosphonium bromide using a similar method to that of Example 48 to give 2-benzyloxy-1-phenyl-3-styrylbenzene, which was hydrogenated using a similar method to that of Reference Example 29 to give 2-(2-phenethyl)-6-pherylphenol.

Sources & evidence

ORD record
ord-a57d1379986f4953b5c720ad8829e197
Source dataset
uspto-grants-1999_10
Patent number
US05965741

Reaction notes

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