HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methyl 3-benzyloxycarbonylmethoxy-5-hydroxybenzoate → Methyl 3-carboxymethoxy-5-hydroxybenzoate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methyl 3-benzyloxycarbonylmethoxy-5-hydroxybenzoate | HCID 21838035 | — |
| Catalyst | Palladium | HCID 23938 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | Methyl 3-carboxymethoxy-5-hydroxybenzoate | HCID 11253108 | 103.5% |
Reaction Steps
10% palladium on carbon (0.1 g) was added to a mixture of methyl 3-benzyloxycarbonylmethoxy-5-hydroxybenzoate (1 g) in methanol (20 ml) and the mixture was subjected to catalytic reduction at ambient temperature under atmospheric pressure. The catalyst was removed by filtration and the filtrate was evaporated in vacuo to give methyl 3-carboxymethoxy-5-hydroxybenzoate (0.74 g).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05968985 |
| Source dataset | uspto-grants-1999_10 |
| ORD ID | ord-ab7f2c9943814927bc5b195fdfcfcd25 |
| Source note | uspto-grants-1999_10 |