3-Phenylbenzaldehyde → HCID 22117819, compound

HRID 1740449Notes

Reaction equation

[NH2:1][C:2]1[CH2:7][C:6]([CH3:9])([CH3:8])[CH2:5][C:4](=[O:10])[CH:3]=1.[C:11]1([C:17]2[CH:18]=[C:19]([CH:22]=[CH:23][CH:24]=2)[CH:20]=O)[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1>>[C:17]1([C:11]2[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=2)[CH:24]=[CH:23][CH:22]=[C:19]([CH:20]2[C:3]3[C:4](=[O:10])[CH2:5][C:6]([CH3:9])([CH3:8])[CH2:7][C:2]=3[NH:1][C:2]3[CH2:7][C:6]([CH3:9])([CH3:8])[CH2:5][C:4](=[O:10])[C:3]2=3)[CH:18]=1

Participants

Reactant 2

HCID 1210533-Phenylbenzaldehyde

HCID 1366803-Amino-5,5-dimethyl-2-cyclohexen-1-one

Product 1

HCID 22117819HCID 22117819, compound

Procedure

3-Amino-5,5-dimethyl-2-cyclohexen-1-one was reacted with 3-phenylbenzaldehyde in an analogous manner to that described in Example 1 to give 9-(3-biphenylyl)-3,4,6,7,9,10-hexahydro-3,3,6,6-tetramethyl-1,8(2H,5H)-acridinedione. Crystallization from ethanol gave a pale yellow crystalline solid of melting point 227-229° C.

Sources & evidence

ORD record: ord-a89d187dfb764fe59961add80e8c38ae
Source dataset: uspto-grants-1999_10
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05969139

Reaction notes

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