3-Amino-5,5-dimethyl-2-cyclohexen-1-one → HCID 22117863, compound

HRID 1740451Notes

Reaction equation

HRID 1740451 reaction equation
[NH2:1][C:2]1[CH2:7][C:6]([CH3:9])([CH3:8])[CH2:5][C:4](=[O:10])[CH:3]=1.[CH3:11][C:12]1[CH:26]=[CH:25][C:15]([O:16][C:17]2[CH:18]=[C:19]([CH:22]=[CH:23][CH:24]=2)[CH:20]=O)=[CH:14][CH:13]=1>>[CH3:8][C:6]1([CH3:9])[CH2:7][C:2]2[NH:1][C:2]3[CH2:7][C:6]([CH3:9])([CH3:8])[CH2:5][C:4](=[O:10])[C:3]=3[CH:20]([C:19]3[CH:22]=[CH:23][CH:24]=[C:17]([O:16][C:15]4[CH:25]=[CH:26][C:12]([CH3:11])=[CH:13][CH:14]=4)[CH:18]=3)[C:3]=2[C:4](=[O:10])[CH2:5]1

Participants

3

Reactant 2

HCID 1366803-Amino-5,5-dimethyl-2-cyclohexen-1-oneHCID 6113073-(4-Methylphenoxy)benzaldehyde

Product 1

HCID 22117863HCID 22117863, compound

Procedure

3-Amino-5,5-dimethyl-2-cyclohexen-1-one was reacted with 3-(4-methylphenoxy)benzaldehyde in an analogous manner to that described in Example 1 to give 3,4,6,7,9,10-hexahydro-3,3,6,6-tetramethyl-9-[3-(4-methylphenoxy)-phenyl]-1,8(2H,5H)-acridinedione. Crystallization from ethanol gave a pale yellow crystalline solid of melting point 202-203° C.

Sources & evidence

ORD record
ord-6ca1904dc7ab4fd49005df9fb0e621c8
Source dataset
uspto-grants-1999_10
Patent number
US05969139

Reaction notes

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