2-Bromobenzaldehyde → HCID 14573955, compound

HRID 1740455Notes

Reaction equation

HRID 1740455 reaction equation
[NH2:1][C:2]1[CH2:7][C:6]([CH3:9])([CH3:8])[CH2:5][C:4](=[O:10])[CH:3]=1.[Br:11][C:12]1[CH:19]=[CH:18][CH:17]=[CH:16][C:13]=1[CH:14]=O>>[Br:11][C:12]1[CH:19]=[CH:18][CH:17]=[CH:16][C:13]=1[CH:14]1[C:3]2[C:4](=[O:10])[CH2:5][C:6]([CH3:9])([CH3:8])[CH2:7][C:2]=2[NH:1][C:2]2[CH2:7][C:6]([CH3:9])([CH3:8])[CH2:5][C:4](=[O:10])[C:3]1=2

Participants

3

Reactant 2

HCID 811292-BromobenzaldehydeHCID 1366803-Amino-5,5-dimethyl-2-cyclohexen-1-one

Product 1

HCID 14573955HCID 14573955, compound

Procedure

3-Amino-5,5-dimethyl-2-cyclohexen-1-one was reacted with 2-bromobenzaldehyde in an analogous manner to that described in Example 1 to give 9-(2-bromophenyl)-3,4,6,7,9,10-hexahydro-3,3,6,6-tetramethyl-1,8(2H,5H)-acridinedione. Crystallization from dimethylformamide/water gave a yellow powder of melting point >285° C. (decomposition).

Sources & evidence

ORD record
ord-26391ed3d9d14d9dbfed6b14aa1a5f32
Source dataset
uspto-grants-1999_10
Patent number
US05969139

Reaction notes

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