4-(Dimethylamino)Benzaldehyde → HCID 54408207, compound

HRID 1740508Notes

Reaction equation

HRID 1740508 reaction equation
CN([CH:4]=[CH:5][C:6]1[C:11]([N+:12]([O-:14])=[O:13])=[CH:10][C:9]([N+:15]([O-:17])=[O:16])=[CH:8][C:7]=1[N+:18]([O-:20])=[O:19])C.CN(C=C[C:26]1[C:31]([N+]([O-])=O)=[CH:30][C:29]([N+]([O-])=O)=[CH:28][C:27]=1[NH2:38])C.[CH3:39][C:40]1C([N+]([O-])=O)=CC([N+]([O-])=O)=CC=1[N+]([O-])=O.CN(C)[C:57]1C=CC(C=O)=C[CH:58]=1>>[CH2:39]([N:38]([C:27]1[CH:26]=[CH:31][C:30]([CH:4]=[CH:5][C:6]2[C:11]([N+:12]([O-:14])=[O:13])=[CH:10][C:9]([N+:15]([O-:17])=[O:16])=[CH:8][C:7]=2[N+:18]([O-:20])=[O:19])=[CH:29][CH:28]=1)[CH2:57][CH3:58])[CH3:40]

Participants

5

Reactant 4

HCID 74794-(Dimethylamino)BenzaldehydeHCID 83762,4,6-TrinitrotolueneHCID 54382168N,N-Dimethyl-2-(2,4,6-trinitrophenyl)ethen-1-amineHCID 54479791HCID 54479791, compound

Product 1

HCID 54408207HCID 54408207, compound

Procedure

In addition to the NLO materials β-N,N-Dimethylamino-2,4,6-trinitrostyrene and β-N,N-Dimethylamino-2-amino-4,6-dinitrostyrene mentioned hereinbelow, reaction of TNT with 4-dimethylaminobenzaldehyde in place of dimethylformamide dimethylacetal yields β-[4-(N,N-Diethylamino)phenyl]-2,4,6-trinitrostyrene.

Sources & evidence

ORD record
ord-59b5e8e29bc94742b4123aa51d990218
Source dataset
uspto-grants-1999_10
Patent number
US05969155

Reaction notes

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