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HRID1741971

反应详情

EQUATION

反应方程式

HRID 1741971 的结构方程式

REACTANTS

反应物

2
结构：COCOC1CCCC(=O)C1
HCID10855741

未命名化合物

结构：CC(=O)OC1C(O[Si](C)(C)C(C)(C)C)CC(=O)C(CO)C1O[Si](C)(C)C(C)(C)C
HCID19010980

未命名化合物

PRODUCTS

生成物

1
结构：CC(=O)OC1C(O[Si](C)(C)C(C)(C)C)CC2=CC(=O)OCC2C1O[Si](C)(C)C(C)(C)C
HCID19011016

未命名化合物

收率 34%

PROCEDURE

实验过程

Example 4 was repeated except that 4-acetoxy-3,5-bis(tert-butyldimethylsilyloxy)-2-hydroxymethylcyclohexanone was used instead of 2-hydroxymethyl-3,4-dimethylmethylenedioxy)-5-(methoxymethoxy)cyclohexanone to give 7-acetoxy-6,8-bis(tert-butyldimethylsilyloxy)-1,5,6,7,8,8a-hexahydro-3H-2-benzopyran-3-one having the following property (yield 34%).