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HRID1742064

反应详情

EQUATION

反应方程式

HRID 1742064 的结构方程式

REACTANTS

反应物

3
结构：O
HCID962

Water

H2O

结构：CC(=O)OC(C)=O
HCID7918

Acetic anhydride

C4H6O3

结构：Cc1ccc(S(=O)(=O)ON=C(c2cccc([N+](=O)[O-])c2)n2nc(C)cc2N)cc1
HCID73508419

未命名化合物

PRODUCTS

生成物

1
结构：CC(=O)Nc1cc(C)nn1C(=NOS(=O)(=O)c1ccc(C)cc1)c1cccc([N+](=O)[O-])c1
HCID73508417

未命名化合物

收率 86%

PROCEDURE

实验过程

2 g (4.8 mmol) of 5-amino-3-methyl-1-(O-tosyl-3-nitrobenzohydroximoyl)-pyrazole are heated for 5 minutes under reflux in 5 ml of acetanhydride. This is then cooled down and hydrolysed with water. The solid mass which forms after a little while is separated off, washed with water, dried in the air and recrystallised from acetonitrile. 1.9 g (86%) of 5-acetamido-3-methyl-1-(O-tosyl-3-nitrobenzohydroximoyl)-pyrazole with a m. pt. of 208°-212° C. (decomp.) are obtained.

WORKUP

后处理

  1. customis separated off
  2. washwashed with water
  3. customdried in the air
  4. customrecrystallised from acetonitrile