HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hexamethyldisilazane → 1,1,1-Trichloro-N-(trimethylsilyl)silanamine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hexamethyldisilazane | HCID 13838 | — |
| Reactant | Silicon tetrachloride | HCID 24816 | — |
| Product | 1,1,1-Trichloro-N-(trimethylsilyl)silanamine | HCID 12540015 | 88.6% |
Reaction Steps
In accordance with J. P. Moser, H. Noth and W. Tinhof in Z. Naturforsch. B 29, 166 (1974), 68.98 g (0.406 mol) silicon tetrachloride and 12.3 g (0.076 mol) hexamethyl disilazane are combined in a 250 ml three-necked flask and stirred for 14 hours at room temperature. Subsequent fractional distillation in a short Vigreux column gives 15 g (88%) of the colorless liquid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05340561 |
| Source dataset | uspto-grants-1994_08 |
| ORD ID | ord-0c41560876fb43c69d24d73658b5fbe1 |
| Source note | uspto-grants-1994_08 |