HuagongsheHuagongshe Chemistry Print Report · For research reference only
1,1,3-Trichloropropene → 2-(3,3-Dichloro-2-propenyl)-2-(4-(trifluoromethoxy)benzyl)malononitrile
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1,1,3-Trichloropropene | HCID 17378 | — |
| Reactant | Sodium hydride | HCID 24758 | — |
| Reactant | (4-(Trifluoromethoxy)benzyl)malononitrile | HCID 22235052 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | 2-(3,3-Dichloro-2-propenyl)-2-(4-(trifluoromethoxy)benzyl)malononitrile | HCID 22234985 | 28% |
Reaction Steps
Using 0.20 g of (4-(trifluoromethoxy)benzyl)malononitrile, 5 ml of N,N-dimethylformamide, 50 mg of sodium hydride (60% in oil), and 0.17 ml of 1,1,3-trichloropropene, and according to the process described in the Production Example 1, there was obtained 80 mg of 2-(3,3-dichloro-2-propenyl)-2-(4-(trifluoromethoxy)benzyl)malononitrile (the present compound (28)).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07011838B2 |
| Source dataset | uspto-grants-2006_03 |
| ORD ID | ord-5cf97dab61754e9e98007740576c729b |
| Source note | uspto-grants-2006_03 |