HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-Benzyloxy-5-trimethylstannyl-pyridine → [4-(6-Benzyloxy-pyridin-3-yl)-2-nitro-phenyl]-carbamic acid tert.-butyl ester
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-Benzyloxy-5-trimethylstannyl-pyridine | HCID 22224741 | — |
| Reactant | Tert-butyl (4-iodo-2-nitrophenyl)carbamate | HCID 23554339 | — |
| Product | [4-(6-Benzyloxy-pyridin-3-yl)-2-nitro-phenyl]-carbamic acid tert.-butyl ester | HCID 69592778 | 103.9% |
Reaction Steps
Prepared from (4-iodo-2-nitro-phenyl)-carbamic acid tert.-butyl ester (Example A1) (728 mg, 2.0 mmol) and 2-(phenylmethoxy)-5-(trimethylstannyl)-pyridine (766 mg, 2.2 mmol) [CAS-No. [188881-22-3], WO 9709311] according to the general procedure E. Obtained as a yellow solid (876 mg).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07018998B2 |
| Source dataset | uspto-grants-2006_03 |
| ORD ID | ord-b5411286f7b14b83b76340683c8f0af0 |
| Source note | uspto-grants-2006_03 |