HuagongsheHuagongshe Chemistry Print Report · For research reference only
Trimethylsilylacetylene → (2-Nitro-4-trimethylsilanylethynyl-phenyl)-carbamic acid tert.-butyl ester
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Trimethylsilylacetylene | HCID 66111 | — |
| Reactant | Tert-butyl (4-iodo-2-nitrophenyl)carbamate | HCID 23554339 | — |
| Product | (2-Nitro-4-trimethylsilanylethynyl-phenyl)-carbamic acid tert.-butyl ester | HCID 67289195 | 107.6% |
Reaction Steps
Prepared from (4-iodo-2-nitro-phenyl)-carbamic acid tert.-butyl ester (Example A1) (3.64 g, 10 mmol) and trimethylsilylacetylene (4.2 mL, 30 mmol) according to the general procedure F. Obtained as a green oil (3.6 g).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07018998B2 |
| Source dataset | uspto-grants-2006_03 |
| ORD ID | ord-b2ad639086d6411d8206fe331b1e528e |
| Source note | uspto-grants-2006_03 |