HCID 69592821, compound → HCID 69592805, compound

HRID 1745488Notes

Reaction equation

HRID 1745488 reaction equation
[C:1]([O:5][C:6](=[O:25])[NH:7][C:8]1[CH:13]=[CH:12][C:11]([C:14]2[CH:19]=[CH:18][C:17]([CH2:20][CH3:21])=[CH:16][CH:15]=2)=[CH:10][C:9]=1[N+:22]([O-])=O)([CH3:4])([CH3:3])[CH3:2]>[Ni]>[C:1]([O:5][C:6](=[O:25])[NH:7][C:8]1[CH:13]=[CH:12][C:11]([C:14]2[CH:15]=[CH:16][C:17]([CH2:20][CH3:21])=[CH:18][CH:19]=2)=[CH:10][C:9]=1[NH2:22])([CH3:3])([CH3:2])[CH3:4]

Participants

3

Reactant 1

HCID 69592821HCID 69592821, compound

Product 1

HCID 69592805HCID 69592805, compound

Reagents, catalysts & solvents 1

HCID 935NickelCatalyst

Procedure

Prepared from (4′-ethyl-3-nitro-biphenyl-4-yl)-carbamic acid tert.-butyl ester (Example B4) by catalytic hydrogenation with Raney-Ni according to the general procedure G (method a). Obtained as a white solid (311 mg).

Sources & evidence

ORD record
ord-be6261dcd7a2491abd1c9913ce3a56c9
Source dataset
uspto-grants-2006_03
Patent number
US07018998B2

Reaction notes

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