(3'-Methyl-3-nitro-biphenyl-4-yl)-carbamic acid tert.-butyl ester → HCID 69592798, compound

HRID 1745500Notes

Reaction equation

HRID 1745500 reaction equation
[C:1]([O:5][C:6](=[O:24])[NH:7][C:8]1[CH:13]=[CH:12][C:11]([C:14]2[CH:19]=[CH:18][CH:17]=[C:16]([CH3:20])[CH:15]=2)=[CH:10][C:9]=1[N+:21]([O-])=O)([CH3:4])([CH3:3])[CH3:2]>[Ni]>[C:1]([O:5][C:6](=[O:24])[NH:7][C:8]1[CH:13]=[CH:12][C:11]([C:14]2[CH:19]=[CH:18][CH:17]=[C:16]([CH3:20])[CH:15]=2)=[CH:10][C:9]=1[NH2:21])([CH3:4])([CH3:2])[CH3:3]

Participants

3

Reactant 1

HCID 69592827(3'-Methyl-3-nitro-biphenyl-4-yl)-carbamic acid tert.-butyl ester

Product 1

HCID 69592798HCID 69592798, compound

Reagents, catalysts & solvents 1

HCID 935NickelCatalyst

Procedure

Prepared from (3′-methyl-3-nitro-biphenyl-4-yl)-carbamic acid tert.-butyl ester (Example C6) by catalytic hydrogenation with Raney-Ni according to the general procedure G (method a). Obtained as a white powder (212 mg).

Sources & evidence

ORD record
ord-4dada9614604497d80ea2683752111d1
Source dataset
uspto-grants-2006_03
Patent number
US07018998B2

Reaction notes

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