HCID 69592819, compound → HCID 69592834, compound

HRID 1745501Notes

Reaction equation

HRID 1745501 reaction equation
[C:1]([O:5][C:6](=[O:25])[NH:7][C:8]1[CH:13]=[CH:12][C:11]([C:14]2[CH:19]=[CH:18][C:17]([Cl:20])=[C:16]([Cl:21])[CH:15]=2)=[CH:10][C:9]=1[N+:22]([O-])=O)([CH3:4])([CH3:3])[CH3:2]>[Ni]>[C:1]([O:5][C:6](=[O:25])[NH:7][C:8]1[CH:13]=[CH:12][C:11]([C:14]2[CH:19]=[CH:18][C:17]([Cl:20])=[C:16]([Cl:21])[CH:15]=2)=[CH:10][C:9]=1[NH2:22])([CH3:4])([CH3:2])[CH3:3]

Participants

3

Reactant 1

HCID 69592819HCID 69592819, compound

Product 1

HCID 69592834HCID 69592834, compound

Reagents, catalysts & solvents 1

HCID 935NickelCatalyst

Procedure

Prepared from (3′,4′-dichloro-3-nitro-biphenyl-4-yl)-carbamic acid tert.-butyl ester (Example C7) by catalytic hydrogenation with Raney-Ni according to the general procedure G (method a). Obtained as a white solid (485 mg).

Sources & evidence

ORD record
ord-6a58100a274e496eb197712d9505e702
Source dataset
uspto-grants-2006_03
Patent number
US07018998B2

Reaction notes

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