HRID1746263

反应详情

EQUATION

反应方程式

REACTANTS

反应物

$结构：C/C(=N\OCc1ccccc1)c1ccc(-n2c(=O)[nH][nH]c2=O)cc1$

HCID89392333

未命名化合物

PRODUCTS

生成物

$结构：C/C(=N\OCc1ccccc1)c1ccc(N2C(=O)N=NC2=O)cc1$

HCID89392357

未命名化合物

收率 52%

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID6344

Dichloromethane

CH2Cl2

PROCEDURE

实验过程

To (E)-4-(4-(1-(benzyloxyimino)ethyl)phenyl)-1,2,4-triazolidine-3,5-dione (I-5a: 56 mg, 0.173 mmol) in CH2Cl2 (1.727 mL) was added SiO2—HNO3 (112 mg). The mixture was stirred at room temperature for 30 minutes, filtered, concentrated in vacuo and dried to give (E)-4-(4-(1-(benzyloxyimino)ethyl)phenyl)-3H-1,2,4-triazole-3,5(4H)-dione (I-4b: 29 mg, 52%) as a red solid. 1H NMR (400 MHz, CD3CN) δ ppm 2.31 (s, 3 H) 5.28 (s, 2 H) 7.38 (d, J=7.07 Hz, 1 H) 7.43 (t, J=7.20 Hz, 2 H) 7.46-7.54 (m, 4 H) 7.86-7.94 (m, 2 H).

WORKUP

后处理

filtrationfiltered
concentrationconcentrated in vacuo
customdried