HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1746338Generated: November 1, 2026
Isopropanol → [[1,1'-Bi(cyclohexane)]-1-yl]methanol
https://huagongshe.com/reaction/1746338
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Isopropanol | HCID 3776 | — |
| Reactant | (1,1'-Biphenyl)-2-carboxaldehyde | HCID 121052 | — |
| Reactant | HCID 178418361 | HCID 178418361 | — |
| Product | [[1,1'-Bi(cyclohexane)]-1-yl]methanol | HCID 21527964 | 80% |
Reaction Steps
To a 5000 ml autoclave, 910 g of 2-propanol (IPA, Wako Pure Chemical Industries, special grade), 364 g of biphenyl aldehyde made by Mitsubishi Gas Chemical (2.0 mol), 7.3 g of 5% Ru/Al2O3 (made by N. E. CHEMCAT) and 10 MPa of hydrogen were charged, and stirred at 150° C. for 8 h. After cooling, a catalyst was filtered under an inert gas atmosphere. After a solvent was removed, distillation was conducted under reduced pressure to obtain bicyclohexyl methanol (BCHM) (80% yield, 99% purity).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US09150491B2 |
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| Source dataset | uspto-grants-2015_10 |
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| ORD ID | ord-daed2e528e384ca9a966ab710947e4fd |
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| Source note | uspto-grants-2015_10 |
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