참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Nitric Acid | HCID 944 | — |
| 반응물 | Water | HCID 962 | — |
| 반응물 | 1,4-Bis(2-ethylhexyloxy)benzene | HCID 3579920 | — |
| 용매 | Chloroform | HCID 6212 | — |
| 생성물 | 1,4-Bis(2-ethylhexyloxy)-2-nitrobenzene | HCID 89601589 | 100% |
반응 단계
1,4-Bis(2-ethylhexyloxy)benzene (50.2 g, 0.150 mol) is dissolved in chloroform (150 ml) and cooled to 0° C. Nitric acid (70%, 17.0 g, 0.190 mol) is added dropwise at 0-3° C. and the reaction stirred whilst monitoring progress by HPLC. After 60 minutes, water (50 ml) is added and the organic layer separated, dried (MgSO4) and evaporated to give the title compound as a yellow oil (56.9 g, 100%). The material is used without further purification.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US09152006B2 |
|---|
| 출처 데이터셋 | uspto-grants-2015_10 |
|---|
| ORD ID | ord-bd3229c156e54d48bbee33e5a984c392 |
|---|
| 출처 메모 | uspto-grants-2015_10 |
|---|
