Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Phenylboronic Acid | HCID 66827 | — |
| Reactant | (2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanal | HCID 107526 | — |
| Reactant | 2-(Dihydroxyboranyl)benzoic acid | HCID 2733985 | — |
| Reactant | 1-Ethyl-3-methylimidazolium chloride | HCID 2734160 | — |
| Solvent | Dimethylacetamide | HCID 31374 | — |
| Product | D-(-)-Fructose | HCID 5984 | — |
Reaction Steps
Glucose (49.5 mg, 275 μmol), 2-carboxyphenylboronic acid (45.9 mg, 277 μmol) or other phenylboronic acid (as indicated) and MgO (36.6 mg, 908 μmol) were mixed in DMA or [EMIM]Cl (500 mg). The reaction mixture was heated at 120° C. for 4 h. At 1-h intervals, aliquots of the reaction mixture were removed for analysis by HPLC.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US09162999B2 |
|---|
| Source dataset | uspto-grants-2015_10 |
|---|
| ORD ID | ord-e538e07c080242878556e2b688c7b27b |
|---|
| Source note | uspto-grants-2015_10 |
|---|
