HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1752549Generated: October 27, 2026
Benzyl azide → 1-Benzyl-5-phenyl-4-(tributylstannyl)-1H-1,2,3-triazole
https://huagongshe.com/reaction/1752549
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Benzyl azide | HCID 12152 | — |
| Reactant | Tributyl(2-phenylethynyl)stannane | HCID 630640 | — |
| Product | 1-Benzyl-5-phenyl-4-(tributylstannyl)-1H-1,2,3-triazole | HCID 68738217 | — |
Reaction Steps
Phenylethynyltri-n-butyltin (8.25 g, 21.1 mmol) and benzyl azide (2.3 mL, 18.4 mmol) were combined and heated to 150° C. overnight. The mixture was purified by silica gel chromatography eluting with a gradient of 5-40% ethyl acetate in hexanes to afford the title compound. MS (ESI+) m/z 526.3 (M+H)+.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US09163007B2 |
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| Source dataset | uspto-grants-2015_10 |
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| ORD ID | ord-93ee724589fb4346b18db5684a1ec753 |
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| Source note | uspto-grants-2015_10 |
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