HuagongsheHuagongshe Chemistry Print Report · For research reference only
N-bromobutanimide → Methyl 3-bromo-5-formyl-4-hydroxybenzoate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | N-bromobutanimide | HCID 67184 | — |
| Reactant | Benzoic acid, 3-formyl-4-hydroxy-, methyl ester | HCID 212595 | — |
| Product | Methyl 3-bromo-5-formyl-4-hydroxybenzoate | HCID 71711084 | 73% |
Reaction Steps
Proceeding as in Reference 9, but substituting methyl 3-formyl-4-hydroxybenzoate (12.0 g, 66.6 mmol, 1 eq.) and N-bromosuccinimide (12.45 g, 69.9 mmol, 1.05 eq.) gave methyl 3-bromo-5-formyl-4-hydroxybenzoate (12.6 g) as a white solid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09162986B2 |
| Source dataset | uspto-grants-2015_10 |
| ORD ID | ord-0ca128939f5f4bfeba422e0170f51a61 |
| Source note | uspto-grants-2015_10 |