m-Chloroperbenzoic acid → HCID 66779928, compound

Participants

Reaction Steps

Product from step 2 (10.0 g, 38.5 mmol) was dissolved in 50 mL of dichloromethane and added dropwise into a solution of 3-chloroperoxybenzoic acid (99.3 g, 42.4 mmol) in dichloromethane (50 mL). The mixture was stirred for 24 h and then filtered. The solution obtained was washed twice with NaHCO3 (2 M) and once with brine. The extracted product was then purified by column chromatography (by silica gel using hexane/EtOAc gradient as eluent). The monomer was obtained as a white crystalline powder. Yield: 70%.

Provenance & Evidence