HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methanol → Methyl 5-amino-o-anisate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methanol | HCID 887 | — |
| Reactant | Sodium Sulfate | HCID 24436 | — |
| Reactant | Methyl 5-nitrosalicylate | HCID 87041 | — |
| Catalyst | Palladium | HCID 23938 | — |
| Product | Methyl 5-amino-o-anisate | HCID 89843 | — |
Reaction Steps
The hydrogenation of methyl 2-hydroxy-5-nitrobenzoate (700 mg, 3.3 mmol) using 10% Pd—C (100 mg) and Na2SO4 (100 mg) in MeOH at 50 psi gave methyl 5-amino-2-methoxybenzoate (600 mg).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09162989B2 |
| Source dataset | uspto-grants-2015_10 |
| ORD ID | ord-c55fd01108204982b3e912de883fb994 |
| Source note | uspto-grants-2015_10 |