化工社化工社 化学情報印刷レポート · 研究参考用
2-Nitrotoluene → Azoxybenzene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 2-Nitrotoluene | HCID 6944 | — |
| 反応物 | Nitrobenzene | HCID 7416 | — |
| 反応物 | 1-Ethyl-2-nitrobenzene | HCID 69156 | — |
| 生成物 | Azoxybenzene | HCID 10316 | — |
反応手順
The reduction reaction was carried out in the same manner as set forth in Example 6 except for using a mixture of 1.0 mmol of o-methyl nitrobenzene and 1.0 mmol of o-ethyl nitrobenzene instead of using nitrobenzene alone, and using 19.5 mg (the amount required for swelling of the reactant in 100%) of Polymer supported reagent-2, and thereby an azoxybenzene derivative of a symmetrical structure and an azoxybenzene derivative of an asymmetrical structure were obtained as a main product, respectively.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US09169200B2 |
| 出典データセット | uspto-grants-2015_10 |
| ORD ID | ord-5640dc0bf2034804ae5f5c51180f0889 |
| 出典メモ | uspto-grants-2015_10 |