huagongshe.com
HRID1756179

反应详情

EQUATION

反应方程式

HRID 1756179 的结构方程式

REACTANTS

反应物

6
结构：[K+].[OH-]
HCID14797

Potassium hydroxide

HKO

结构：O=Cc1ccc(CO)o1
HCID237332

5-(Hydroxymethyl)-2-furfural

C6H6O3

结构：O=Cc1cccc(CO)c1
HCID13131455

3-(Hydroxymethyl)benzaldehyde

C8H8O2

结构：CCNC/C=C/C#CC(C)(C)C.Cl
HCID19917114

未命名化合物

结构：CCNC/C=C/C#CC(C)(C)OC.Cl
HCID19917137

未命名化合物

结构：CCOC(=O)/C=C/c1cccc(CN(CC)CC=CC#CC(C)(C)C)c1
HCID86747792

未命名化合物

PRODUCTS

生成物

1
结构：CCN(CC=CC#CC(C)(C)C)Cc1cccc(/C=C/C(=O)O)c1
HCID86747791

未命名化合物

PROCEDURE

实验过程

When ethyl (E)-3-(N-ethyl-6,6-dimethyl-2-hepten-4-ynylaminomethyl)cinnamate, prepared by using 3-hydroxymethylbenzaldehyde and (E)-N-ethyl-6,6-dimethyl-2-hepten-4-ynylamine hydrochloride instead of the starting 5-hydroxymethyl-2-furaldehyde and (E)-N-ethyl-6-methoxy-6-methyl-2-hepten-4-ynylamine hydrochloride as in Referential Example 46, is hydrolyzed with potassium hydroxide, (E)-3-(N-ethyl-6,6-dimethyl-2-hepten-4-ynylaminomethyl) cinnamic acid is obtained.