HCID 10245859, compound → HCID 21474541, compound

HRID 1756458Notes

Reaction equation

HRID 1756458 reaction equation
[C:1]([C:5]1[CH:6]=[C:7]([CH:11]=[CH:12][C:13]=1[O:14][Si:15]([C:18]([CH3:21])([CH3:20])[CH3:19])([CH3:17])[CH3:16])[C:8](Cl)=[O:9])([CH3:4])([CH3:3])[CH3:2].[OH:22][CH2:23][C:24]1[CH:35]=[CH:34][C:27]([C:28]([O:30][CH2:31][CH:32]=[CH2:33])=[O:29])=[CH:26][CH:25]=1>>[C:1]([C:5]1[CH:6]=[C:7]([CH:11]=[CH:12][C:13]=1[O:14][Si:15]([C:18]([CH3:21])([CH3:20])[CH3:19])([CH3:17])[CH3:16])[C:8]([O:22][CH2:23][C:24]1[CH:25]=[CH:26][C:27]([C:28]([O:30][CH2:31][CH:32]=[CH2:33])=[O:29])=[CH:34][CH:35]=1)=[O:9])([CH3:4])([CH3:3])[CH3:2]

Participants

3

Reactant 2

HCID 10245859HCID 10245859, compoundHCID 22392687Allyl 4-hydroxymethylbenzoate

Product 1

HCID 21474541HCID 21474541, compound

Procedure

In a manner similar to Example 1(d), by reaction of 4.9 g (15 mmol) of 3-tert-butyl-4-(tert-butyldimethylsilyloxy)benzoyl chloride with 2.9 g (15 mmol) of allyl 4-hydroxymethylbenzoate, 4.1 g (60%) of the allyl ester are obtained in the form of a slightly yellow oil.

Workup

  1. customare obtained in the form of a slightly yellow oil

Sources & evidence

ORD record
ord-962de2d63cee40e5a47d6a01239f0c97
Source dataset
uspto-grants-1995_08
Patent number
US05439925

Reaction notes

Loading…