HuagongsheHuagongshe Chemistry Print Report · For research reference only
Di-tert-butyl peroxide → HCID 15169991, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Di-tert-butyl peroxide | HCID 8033 | — |
| Reactant | Cyclohexene | HCID 8079 | — |
| Reactant | 1-Hydroxy-4-benzoyloxy-2,2,6,6-tetramethylpiperidine | HCID 688178 | — |
| Product | HCID 15169991 | HCID 15169991 | 81% |
Reaction Steps
A solution of 33.6 grams (122 mmol) of 4-benzoyloxy-1-oxyl-2,2,6,6-tetramethylpiperidine, 23.0 grams (157 mmol) of di-tert-butyl peroxide, and 70 ml of cyclohexene is heated in a Fischer-Porter pressure bottle at 138° C. for 6.5 hours. The reaction mixture is purified by flash chromatography on silica gel (200:1 heptane:ethyl acetate) to afford 35.1 grams (81% yield) of the title compound as a colorless oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05442071 |
| Source dataset | uspto-grants-1995_08 |
| ORD ID | ord-57f96413211143bda13a8dc7dc8c4402 |
| Source note | uspto-grants-1995_08 |