ethyl (+/-)-5-decyl-alpha-phenyl-2H-tetrazole-2-acetate → (+/-)-5-(dodecylthio)-alpha-phenyl-2H-tetrazole-2-acetic acid

HRID 1756933Notes

Reaction equation

HRID 1756933 reaction equation
[CH2:1]([S:13][C:14]1[N:15]=[N:16][N:17]([CH:19]([C:25]2[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=2)[C:20]([O:22]CC)=[O:21])[N:18]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].C(C1N=NN(C(C2C=CC=CC=2)C(OCC)=O)N=1)CCCCCCCCC>>[CH2:1]([S:13][C:14]1[N:15]=[N:16][N:17]([CH:19]([C:25]2[CH:26]=[CH:27][CH:28]=[CH:29][CH:30]=2)[C:20]([OH:22])=[O:21])[N:18]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12]

Participants

3

Reactant 2

HCID 19391039ethyl (+/-)-5-decyl-alpha-phenyl-2H-tetrazole-2-acetateHCID 54159318ethyl (+/-)-5-(dodecylthio)-alpha-phenyl-2H-tetrazole-2-acetate

Product 1

HCID 21469499(+/-)-5-(dodecylthio)-alpha-phenyl-2H-tetrazole-2-acetic acid

Procedure

When in the general procedure of Example 79 an appropriate amount of ethyl (±)-5-(dodecylthio)-α-phenyl-2H-tetrazole-2-acetate was substituted for ethyl (±)-5-decyl-α-phenyl-2H-tetrazole-2-acetate, the title compound was obtained, mp 64°-67° C.

Sources & evidence

ORD record
ord-723a150e19f84018a4768e4fff4aedb4
Source dataset
uspto-grants-1995_08
Patent number
US05441975

Reaction notes

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