Pivaloyl chloride → 1-(Tert.-butylcarbonyl)-1-aza-4,7,10,13,16-pentaoxacyclooctadecane

HRID 1757320Notes

Reaction equation

[NH:1]1[CH2:18][CH2:17][O:16][CH2:15][CH2:14][O:13][CH2:12][CH2:11][O:10][CH2:9][CH2:8][O:7][CH2:6][CH2:5][O:4][CH2:3][CH2:2]1.[C:19](Cl)(=[O:24])[C:20]([CH3:23])([CH3:22])[CH3:21]>>[C:20]([C:19]([N:1]1[CH2:18][CH2:17][O:16][CH2:15][CH2:14][O:13][CH2:12][CH2:11][O:10][CH2:9][CH2:8][O:7][CH2:6][CH2:5][O:4][CH2:3][CH2:2]1)=[O:24])([CH3:23])([CH3:22])[CH3:21]

Participants

Reactant 2

HCID 62493Pivaloyl chloride

HCID 1185781,4,7,10,13-Pentaoxa-16-azacyclooctadecane

Product 1

HCID 152187881-(Tert.-butylcarbonyl)-1-aza-4,7,10,13,16-pentaoxacyclooctadecane

Procedure

Analogously to Example 14 from 1-aza-4,7,10,13,16-pentaoxacyclooctadecane and pivalyl chloride.

Sources & evidence

ORD record: ord-88fb69121c904b81b2387ded9c7cc490
Source dataset: uspto-grants-1995_08
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05445762

Reaction notes

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