Diaza-18-crown-6 → 4, 13-Bis(2,2-dimethylbutyroyl)-1,7,10,16-tetraoxa-4,13-diazacyclooctadecane

HRID 1757327Notes

Reaction equation

HRID 1757327 reaction equation
[O:1]1[CH2:18][CH2:17][O:16][CH2:15][CH2:14][NH:13][CH2:12][CH2:11][O:10][CH2:9][CH2:8][O:7][CH2:6][CH2:5][NH:4][CH2:3][CH2:2]1.[CH3:19][C:20]([CH3:26])([CH2:24][CH3:25])[C:21](Cl)=[O:22]>>[CH3:19][C:20]([CH3:26])([CH2:24][CH3:25])[C:21]([N:4]1[CH2:5][CH2:6][O:7][CH2:8][CH2:9][O:10][CH2:11][CH2:12][N:13]([C:21](=[O:22])[C:20]([CH3:26])([CH3:19])[CH2:24][CH3:25])[CH2:14][CH2:15][O:16][CH2:17][CH2:18][O:1][CH2:2][CH2:3]1)=[O:22]

Participants

3

Reactant 2

HCID 72805Diaza-18-crown-6HCID 799582,2-Dimethylbutyryl chloride

Product 1

HCID 218041554, 13-Bis(2,2-dimethylbutyroyl)-1,7,10,16-tetraoxa-4,13-diazacyclooctadecane

Procedure

Analogously to Example 2 from 1,7,10,16-tetraoxa-4,13-diazacyclooctadecane and 2,2-dimethylbutyryl chloride.

Sources & evidence

ORD record
ord-62b62ce90a76468184fb93d118a5e532
Source dataset
uspto-grants-1995_08
Patent number
US05445762

Reaction notes

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