2-Acetylbenzoic acid → HCID 53703504, compound

HRID 1757650Notes

Reaction equation

HRID 1757650 reaction equation
[OH:1][C:2]1[CH:3]=[C:4]([CH:7]=[C:8]([N+:11]([O-:13])=[O:12])[C:9]=1[OH:10])[CH:5]=O.[C:14]([C:17]1[CH:22]=[CH:21][CH:20]=[CH:19][C:18]=1[C:23](=[O:25])[CH3:24])([OH:16])=[O:15]>>[OH:1][C:2]1[CH:3]=[C:4]([CH:5]=[CH:24][C:23]([C:18]2[CH:19]=[CH:20][CH:21]=[CH:22][C:17]=2[C:14]([OH:16])=[O:15])=[O:25])[CH:7]=[C:8]([N+:11]([O-:13])=[O:12])[C:9]=1[OH:10]

Participants

3

Reactant 2

HCID 684742-Acetylbenzoic acidHCID 57489573,4-Dihydroxy-5-nitrobenzaldehyde

Product 1

HCID 53703504HCID 53703504, compound

Procedure

The procedure described in Example 8 was repeated using 1.83 g of 3,4-dihydroxy-5-nitrobenzaldehyde and 1.64 g of 2'-carboxyacetophenone. Yield 0.36 g (11%), m.p. 178-180° C.

Sources & evidence

ORD record
ord-78333954556c419ea214fe914477d382
Source dataset
uspto-grants-1995_08
Patent number
US05446194

Reaction notes

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