HuagongsheHuagongshe Chemistry Print Report · For research reference only
L-Gulose → Sorbitol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | L-Gulose | HCID 80127 | — |
| Reactant | (2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanal | HCID 107526 | — |
| Reactant | aldehydo-L-idose | HCID 111112 | — |
| Product | Sorbitol | HCID 5780 | — |
Reaction Steps
A method for producing L-sugars including L-idose and L-gulose from D-glucose. The method comprises hydrogenating D-glucose to provide sorbitol, oxydizing the D-sorbitol to provide L-sorbose, racemizing the L-sorbose to provide a mixture of L-sorbose, L-idose and L-gulose, and precipitating the L-sorbose with lime from a dilute solution. The unconverted L-sorbose is recovered by carbonation and recycled. The hydrogenation of glucose is done in a fixed catalyst bed.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04371616 |
| Source dataset | uspto-grants-1983_02 |
| ORD ID | ord-ac06f15d678d4692be4c5ad61bca6aaa |
| Source note | uspto-grants-1983_02 |