HRID1758189

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：CC(C)(C1CCC(OCC2CO2)CC1)C1CCC(OCC2CO2)CC1

HCID114514

2,2'-{Propane-2,2-diylbis[(cyclohexane-4,1-diyl)oxymethylene]}bis(oxirane)

C21H36O4

HCID579967

2,2,6,6-tetramethyl-4-piperidyl benzoate

C16H23NO2

PRODUCTS

生成物

结构：CC(C)(C1CCC(OCC(O)CN2C(C)(C)CC(OC(=O)c3ccccc3)CC2(C)C)CC1)C1CCC(OCC(O)CN2C(C)(C)CC(OC(=O)c3ccccc3)CC2(C)C)CC1

HCID20510564

未命名化合物

PROCEDURE

实验过程

A mixture of 30.0 g of 4-benzoyloxy-2,2,6,6-tetramethylpiperidine and 15.0 g of 2,2-bis[4-(2,3-epoxypropoxy)cyclohexyl]propane was reacted folowing the procedure described in Example 5, giving the desired Compound No. 78 in the form of a colourless, viscous liquid. The Compound had an Rf value of 0.70 on thin-layer chromatography on silica gel developed with a 15:5:1 by volume mixture of n-hexane, triethylamine and ethanol.

WORKUP

后处理

customwas reacted

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-8d6e96003f9a4665b6184f1f8fc1b214
来源数据集: uspto-grants-1983_02
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04371644
来源说明: uspto-grants-1983_02

反应 SMILES

[C:1]([O:9][CH:10]1[CH2:15][C:14]([CH3:17])([CH3:16])[NH:13][C:12]([CH3:19])([CH3:18])[CH2:11]1)(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[O:20]1[CH2:44][CH:21]1[CH2:22][O:23][CH:24]1[CH2:29][CH2:28][CH:27]([C:30]([CH:33]2[CH2:38][CH2:37]C(OCC3OC3)CC2)([CH3:32])[CH3:31])[CH2:26][CH2:25]1>>[OH:20][CH:21]([CH2:44][N:13]1[C:12]([CH3:19])([CH3:18])[CH2:11][CH:10]([O:9][C:1](=[O:8])[C:2]2[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=2)[CH2:15][C:14]1([CH3:17])[CH3:16])[CH2:22][O:23][CH:24]1[CH2:25][CH2:26][CH:27]([C:30]([CH:33]2[CH2:26][CH2:25][CH:24]([O:23][CH2:22][CH:21]([OH:20])[CH2:44][N:13]3[C:14]([CH3:17])([CH3:16])[CH2:15][CH:10]([O:9][C:1](=[O:8])[C:2]4[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=4)[CH2:11][C:12]3([CH3:19])[CH3:18])[CH2:37][CH2:38]2)([CH3:32])[CH3:31])[CH2:28][CH2:29]1