Benzenamine hydrochloride (1:1) → Phenol, 4-[1-(4-aminophenyl)-1-methylethyl]-

HRID 1758589Notes

Reaction equation

HRID 1758589 reaction equation
Cl.[NH2:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[C:9]([C:12]1[CH:17]=[CH:16][C:15]([OH:18])=[CH:14][CH:13]=1)([CH3:11])=[CH2:10]>>[OH:18][C:15]1[CH:16]=[CH:17][C:12]([C:9]([C:6]2[CH:7]=[CH:8][C:3]([NH2:2])=[CH:4][CH:5]=2)([CH3:11])[CH3:10])=[CH:13][CH:14]=1

Participants

3

Reactant 2

HCID 8870Benzenamine hydrochloride (1:1)HCID 584247p-Isopropenylphenol

Product 1

HCID 11148864Phenol, 4-[1-(4-aminophenyl)-1-methylethyl]-Yield 76%

Procedure

Example 11 was repeated except that the amount of the aniline hydrochloride was changed to 0.26 g (0.02 mole of catalyst per mole of the p-isopropenyl phenol monomeric unit). After the reaction, the reaction mixture was analyzed by gas chromatography. It was found that 17.3 g (yield 76%) of 2-(4'-hydroxyphenyl)-2-(4'-aminophenyl)-propane and 1.4 g of bisphenol A were formed.

Workup

  1. customAfter the reaction

Sources & evidence

ORD record
ord-3bb3033c18d44fbdb3c9725ea8ec5ba0
Source dataset
uspto-grants-1983_02
Patent number
US04374272

Reaction notes

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