HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzyl Bromide → 1-Benzyl-2-(benzylsulfanyl)pyridin-1-ium bromide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzyl Bromide | HCID 7498 | — |
| Reactant | 2-benzylsulfanylpyridine | HCID 472961 | — |
| Solvent | Diethyl Ether | HCID 3283 | — |
| Product | 1-Benzyl-2-(benzylsulfanyl)pyridin-1-ium bromide | HCID 13435001 | 59.2% |
Reaction Steps
A mixture of 2-(benzylthio)pyridine (2.01 g) and benzyl bromide (1.71 g) was kept at ambient temperature for 4 days. Trituration at length with ether gave a solid which was removed by filtration and dried to give the title compound (2.2 g) mp 125°-7° C. (Found: C, 61.6; H, 5.2; N, 3.6%. C19H18BrNS requires C, 61.3; H, 4.9; N, 3.8%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04374992 |
| Source dataset | uspto-grants-1983_02 |
| ORD ID | ord-7edb2e045f0f4ee5a2e38c7cc20fbd14 |
| Source note | uspto-grants-1983_02 |