HuagongsheHuagongshe Chemistry Print Report · For research reference only
Trimethyl phosphite → Allyl dimethylphosphono-acetate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Trimethyl phosphite | HCID 8472 | — |
| Reactant | Allyl chloroacetate | HCID 76206 | — |
| Product | Allyl dimethylphosphono-acetate | HCID 13267138 | 70.5% |
Reaction Steps
191 g of trimethylphosphite were added dropwise under stirring to 188 g of allyl chloroacetate (21/2 h) preliminarly heated to 118°. The reaction mixture was kept at this temperature for 4 h, whereupon it was subjected to a distillation to give 205 g of allyl dimethylphosphono-acetate, b.p. 118°/0.1 Torr.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04338458 |
| Source dataset | uspto-grants-1982_07 |
| ORD ID | ord-1474bf691ca0491282ccf64a8a5dcdd4 |
| Source note | uspto-grants-1982_07 |