Formic Acid → HCID 86738473, compound

HRID 1759160Notes

Reaction equation

HRID 1759160 reaction equation
[Na:1].OC[O:4][PH:5]([C:7](=[O:14])[CH2:8][CH2:9][C:10]([O:12][CH3:13])=[O:11])=[O:6].C(O)=[O:16]>>[Na:1].[O:14]=[C:7]([P:5]([OH:4])([OH:6])=[O:16])[CH2:8][CH2:9][C:10]([O:12][CH3:13])=[O:11]

Participants

3

Reactant 2

HCID 284Formic AcidHCID 178500587HCID 178500587, compound

Product 1

HCID 86738473HCID 86738473, compound

Procedure

A solution of the product of Example 9 (5.0 g, 0.0215 mol) in formic acid (50 ml) was refluxed for 21/2 hours. The solution was evaporated in vacuo. Toluene (~25 ml) was added to the residue and was evaporated to dryness. This procedure was repeated twice. The NMR spectrum was consistent with the proposed structure.

Workup

  1. customThe solution was evaporated in vacuo
  2. additionToluene (~25 ml) was added to the residue
  3. customwas evaporated to dryness

Sources & evidence

ORD record
ord-a7a98775b245469f8db4e2692a58bca7
Source dataset
uspto-grants-1982_07
Patent number
US04339443

Reaction notes

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