HuagongsheHuagongshe Chemistry Print Report · For research reference only
Nitric Acid → 4-Methoxybenzaldehyde
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Nitric Acid | HCID 944 | — |
| Reactant | 4-Methylanisole | HCID 7731 | — |
| Reactant | Ammonium nitrate | HCID 22985 | — |
| Reactant | Cerium | HCID 23974 | — |
| Product | 4-Methoxybenzaldehyde | HCID 31244 | 94.8% |
Reaction Steps
The same procedure as in Example 1 is repeated except that the cerium salt is electrolyzed with 100 ml of 2 to 3% by weight aqueous solution of nitric acid placed into the cathode chamber in place of ammonium nitrate. p-Methyl anisole is oxidized with the solution withdrawn from the anode chamber to give anisaldehyde in a yield of 94.8%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04339607 |
| Source dataset | uspto-grants-1982_07 |
| ORD ID | ord-792c63817cc344bdad9e73bf61e3152f |
| Source note | uspto-grants-1982_07 |