2-Methoxyethanol → CID 101686797

HRID 1759349Notes

Reaction equation

HRID 1759349 reaction equation
Cl[C:2]1[CH:7]=[CH:6][C:5]([N+:8]([O-:10])=[O:9])=[CH:4][C:3]=1[S:11]([O-:14])(=[O:13])=[O:12].[Na+:15].[CH3:16][O:17][CH2:18][CH2:19][OH:20].[OH-].[Na+]>[O-2].[O-2].[Mn+4].O>[CH3:16][O:17][CH2:18][CH2:19][O:20][C:2]1[CH:7]=[CH:6][C:5]([N+:8]([O-:10])=[O:9])=[CH:4][C:3]=1[S:11]([O-:14])(=[O:13])=[O:12].[Na+:15]

Participants

6

Reactant 3

HCID 80192-MethoxyethanolHCID 14798Sodium HydroxideHCID 70350Benzenesulfonic acid, 2-chloro-5-nitro-, sodium salt (1:1)

Product 1

HCID 101686797CID 101686797

Reagents, catalysts & solvents 2

HCID 178418406HCID 178418406, compoundCatalystHCID 962WaterSolvent

Conditions

Temperature
75 °C

Procedure

A mixture consisting of 5.2 g of sodium 2-chloro-5-nitrobenzenesulfonate, 0.6 g of manganese dioxide, 15 ml of methyl cellosolve, 1 ml of water and 0.95 g of sodium hydroxide was stirred at 75° C. for 40 minutes. After cooling, insoluble substances were removed by filtration and the filtrate was poured into 100 ml of isopropyl alcohol. The crystals thus precipitated were recovered by filtration to obtain 4.8 of sodium 2-(2-methoxyethoxy)-5-nitrobenzenesulfonate. m.p. 238°-239° C.

Workup

  1. temperatureAfter cooling
  2. custominsoluble substances were removed by filtration
  3. additionthe filtrate was poured into 100 ml of isopropyl alcohol
  4. customThe crystals thus precipitated
  5. filtrationwere recovered by filtration

Sources & evidence

ORD record
ord-23b122095a624a0da229c16982963614
Source dataset
uspto-grants-1982_07
Patent number
US04340661

Reaction notes

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