HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethylenediaminetetraacetic Acid → 2-Propenoic acid, butyl ester, polymer with diethenylbenzene and ethenylbenzene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethylenediaminetetraacetic Acid | HCID 6049 | — |
| Reactant | Styrene | HCID 7501 | — |
| Reactant | Butyl Acrylate | HCID 8846 | — |
| Reactant | Trisodium Phosphate | HCID 24243 | — |
| Reactant | Tert-dodecanethiol | HCID 32793 | — |
| Reactant | 1,2-Diethenylbenzene | HCID 66666 | — |
| Reactant | Sodium | HCID 5360545 | — |
| Reactant | CID 21225536 | HCID 21225536 | — |
| Reactant | HCID 86641008 | HCID 86641008 | — |
| Solvent | Water | HCID 962 | — |
| Product | 2-Propenoic acid, butyl ester, polymer with diethenylbenzene and ethenylbenzene | HCID 6454035 | — |
Reaction Steps
65 g styrene, 35 g butyl acrylate, 0.6 g divinylbenzene, 4.5 g disproportionated sodium rosinate, 0.2 g sodium alkylaryl sulfonate, and 200 g water deionized by ion exchange resins are mixed and placed in a polymerization vessel. To the resulting mixture are added 0.1 g p-menthane hydroperoxide, 0.05 g ferrous sulfate, 0.15 g sodium formaldehyde sulfoxylate, 0.07 g sodium salt of EDTA, 0.3 g t-dodecylmercaptan, and 0.5 g sodium phosphate followed by emulsion polymerization at 5° C. for 15 hours to give a styrene-butyl acrylate-divinylbenzene copolymer. Gel content of the resulting crosslinked polymer is 81%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04340660 |
| Source dataset | uspto-grants-1982_07 |
| ORD ID | ord-8387cd7ffaf248d484541fd65f674d3c |
| Source note | uspto-grants-1982_07 |