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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1759469Generated: November 2, 2026

Ethylenediaminetetraacetic Acid → 2-Propenoic acid, butyl ester, polymer with diethenylbenzene and ethenylbenzene

https://huagongshe.com/reaction/1759469

Reaction equation

Participants

RoleNameHCIDCharge
ReactantEthylenediaminetetraacetic AcidHCID 6049—
ReactantStyreneHCID 7501—
ReactantButyl AcrylateHCID 8846—
ReactantTrisodium PhosphateHCID 24243—
ReactantTert-dodecanethiolHCID 32793—
Reactant1,2-DiethenylbenzeneHCID 66666—
ReactantSodiumHCID 5360545—
ReactantCID 21225536HCID 21225536—
ReactantHCID 86641008HCID 86641008—
SolventWaterHCID 962—
Product2-Propenoic acid, butyl ester, polymer with diethenylbenzene and ethenylbenzeneHCID 6454035—

Reaction Steps

65 g styrene, 35 g butyl acrylate, 0.6 g divinylbenzene, 4.5 g disproportionated sodium rosinate, 0.2 g sodium alkylaryl sulfonate, and 200 g water deionized by ion exchange resins are mixed and placed in a polymerization vessel. To the resulting mixture are added 0.1 g p-menthane hydroperoxide, 0.05 g ferrous sulfate, 0.15 g sodium formaldehyde sulfoxylate, 0.07 g sodium salt of EDTA, 0.3 g t-dodecylmercaptan, and 0.5 g sodium phosphate followed by emulsion polymerization at 5° C. for 15 hours to give a styrene-butyl acrylate-divinylbenzene copolymer. Gel content of the resulting crosslinked polymer is 81%.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS04340660
Source datasetuspto-grants-1982_07
ORD IDord-8387cd7ffaf248d484541fd65f674d3c
Source noteuspto-grants-1982_07