HCID 21349241, compound → HCID 53746442, compound

HRID 1759496Notes

Reaction equation

HRID 1759496 reaction equation
[CH3:1][C:2]1([OH:13])[CH2:11][CH2:10][CH2:9][CH:8]2[CH:3]1[CH:4]1[CH2:12][CH:7]2[CH:6]=[CH:5]1>CO.[Pd]>[CH3:1][C:2]1([OH:13])[CH2:11][CH2:10][CH2:9][CH:8]2[CH:3]1[CH:4]1[CH2:12][CH:7]2[CH2:6][CH2:5]1

Participants

4

Reactant 1

HCID 21349241HCID 21349241, compound

Product 1

HCID 53746442HCID 53746442, compound

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 887MethanolSolvent

Procedure

25 g (0.140 mole) of 3-methyl-tricyclo[6.2.1.02,7 ]undec-9-en-3-ol--see Example 1--in 150 ml of methanol were hydrogenated under atmospheric pressure and at room temperature in the presence of 2.5 g of 10% palladium on charcoal. After filtration, evaporation and distillation (b.p. 60°-65°/0.1 Torr), 24 g of a material containing ca. 90% of the desired compound according to vapor phase chromatographic analysis were isolated.

Workup

  1. filtrationAfter filtration, evaporation and distillation (b.p. 60°-65°/0.1 Torr), 24 g of a material
  2. additioncontaining ca. 90% of the desired compound
  3. customwere isolated

Sources & evidence

ORD record
ord-61218d801649411a9043570d6425f2bb
Source dataset
uspto-grants-1982_07
Patent number
US04341666

Reaction notes

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