Acetone → HCID 131712770, compound

HRID 1759501Notes

Reaction equation

HRID 1759501 reaction equation
Cl[CH:2]([O:12][CH2:13][CH:14]([N+:18]([O-:20])=[O:19])[N+:15]([O-:17])=[O:16])[C:3]([N:9]([F:11])[F:10])([N:6]([F:8])[F:7])[CH2:4][F:5].[N-:21]=[N+:22]=[N-:23].[Na+].CC(C)=O>O>[N:21]([CH:2]([O:12][CH2:13][CH:14]([N+:18]([O-:20])=[O:19])[N+:15]([O-:17])=[O:16])[C:3]([N:9]([F:11])[F:10])([N:6]([F:8])[F:7])[CH2:4][F:5])=[N+:22]=[N-:23]

Participants

5

Reactant 3

HCID 180AcetoneHCID 33557Sodium AzideHCID 131712771HCID 131712771, compound

Product 1

HCID 131712770HCID 131712770, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

A mixture of 1.7 g of 1-chloro-2,2-bis(difluoramino)-3-fluorodinitroethoxypropane, 0.7 g of sodium azide, 10 ml of acetone, and 5 ml of water was refluxed for 72 hours. The mixture was extracted with methylene chloride, washed with water, and concentrated to give 1.3 g of light yellow liquid. I.R. showed an absorption for azide at 4.7μ.

Workup

  1. temperaturewas refluxed for 72 hours
  2. extractionThe mixture was extracted with methylene chloride
  3. washwashed with water
  4. concentrationconcentrated
  5. customto give 1.3 g of light yellow liquid
  6. customan absorption for azide at 4.7μ

Sources & evidence

ORD record
ord-2a6e737bf54741659a715aed347efe69
Source dataset
uspto-grants-1982_07
Patent number
US04341712

Reaction notes

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