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1,2-Dichloroethane → N-(1-methylethyl)-3-(4-chlorophenyl)-2-oxiranecarboxamide
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 1,2-Dichloroethane | HCID 11 | — |
| 反応物 | Santonox | HCID 7308 | — |
| 反応物 | m-Chloroperbenzoic acid | HCID 70297 | — |
| 反応物 | N-(1-methylethyl)-4-chlorocinnamoylcarboxamide | HCID 53721062 | — |
| 生成物 | N-(1-methylethyl)-3-(4-chlorophenyl)-2-oxiranecarboxamide | HCID 13041336 | — |
反応手順
This compound was prepared from N-(1-methylethyl)-4-chlorocinnamoylcarboxamide (18.3 g.), m-chloroperbenzoic acid (19.4 g.), 4,4'-thiobis(6-tert-butyl-m-cresol) (0.3 g.), and ethylene dichloride (250 ml.) as described in Example 7, and purified by recrystallization from ether. The compound melted at 139°-141°, and weighed 11.7 g. The analytical sample which was obtained by another recrystallization from ether melted at 143°-145°.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04341718 |
| 出典データセット | uspto-grants-1982_07 |
| ORD ID | ord-b320f5c28d44406384b0a8cd6a627737 |
| 出典メモ | uspto-grants-1982_07 |