HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sulfuryl chloride → Ethyl 2-(2-benzoyloxyethoxyimino)-4-chloro-3-oxobutyrate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sulfuryl chloride | HCID 24648 | — |
| Reactant | Ethyl 2-(2-benzoyloxyethoxyimino)-3-oxobutyrate | HCID 53765835 | — |
| Solvent | Acetic Acid | HCID 176 | — |
| Product | Ethyl 2-(2-benzoyloxyethoxyimino)-4-chloro-3-oxobutyrate | HCID 53906646 | 93.1% |
Reaction Steps
A solution of ethyl 2-(2-benzoyloxyethoxyimino)-3-oxobutyrate (syn isomer, 28 g.), sulfuryl chloride (13.5 g.) and acetic acid (30 ml.) was stirred at 40° C. for 10 minutes and at room temperature for 5.5 hrs. The reaction mixture was treated in a conventional manner to give ethyl 2-(2-benzoyloxyethoxyimino)-4-chloro-3-oxobutyrate (syn isomer, 29 g.).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04341775 |
| Source dataset | uspto-grants-1982_07 |
| ORD ID | ord-16eee1c4626e45f68181f9eeeddede0e |
| Source note | uspto-grants-1982_07 |