HRID1760141

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID10112

Calcium carbonate

CCaO3

3 次

结构：O=S(=O)([N-]S(=O)(=O)C(F)(F)F)C(F)(F)F

HCID4176748

Bis(perfluoromethylsulfonyl)imide anion

C2F6NO4S2-

PRODUCTS

生成物

HCID280

Carbon dioxide

CO2

结构：O=S(=O)([N-]S(=O)(=O)C(F)(F)F)C(F)(F)F.O=S(=O)([N-]S(=O)(=O)C(F)(F)F)C(F)(F)F.[Ca+2]

HCID46242197

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID962

Water

H2O

2 次

PROCEDURE

实验过程

Trifluoromethanesulfonimide ((CF3SO2)2NH, hereinafter HTFSI) was dissolved in water to make a 1 mol/l (1M) solution. Calcium carbonate (CaCO3) was added to the solution with stirring to a molar ratio of 2:1 (HTFSI:CaCO3). A reaction of calcium carbonate and HTFSI produced calcium bistrifluoromethanesulfonimide, carbon dioxide and water as shown below: CaCO3+HTFSI=Ca(TFSI)2+CO2+H2O